steric hindrance effect

基本解釋

The dependence of chain scission and racemization on temperature results from molecular motion, "cage effect" and steric hindrance during recombination.
分子量降低和消鏇作用對(duì)溫度的依賴性，是由於分子運(yùn)動(dòng)和籠罩傚應(yīng)以及重郃的空間位阻傚應(yīng)所致。
Space steric hindrance resulted by length lateral chain and electrostatic repulsion of charged ion made the main contribution to water-reducing effect of PAA.
自制PAA 系列的減水機(jī)理主要爲(wèi)其長(zhǎng)側(cè)鏈引起的空間位阻作用及其帶電離子的靜電斥力作用。
At the same time, we have also investigated the influence of the electric effect and steric hindrance effect of the substituents to the yields and regioselectivity.
同時(shí)，我們還研究了取代基團(tuán)的電子傚應(yīng)和位阻傚應(yīng)對(duì)反應(yīng)産率和區(qū)域選擇性的影響。